Fix outdir path concat

[kojo1]

When both `new_certs_dir` (from config file) and `-out` option are
specified in the `ca` command, the output paths were incorrectly
concatenated.

Bug example:

• Config: `new_certs_dir = /tmp/certs`
• Command: `wolfssl ca -config ca.conf -out /tmp/output/signed.pem ...`
• Result: `/tmp/certs/tmp/output/signed.pem` (wrong)
• Expected: `/tmp/output/signed.pem`

Root Cause

In `wolfCLU_CertSignAppendOut()` (src/x509/clu_x509_sign.c), when appending
the `-out` path to `new_certs_dir`:

1. Absolute paths in `-out` were not detected and should override
   `new_certs_dir`
2. Path separator `/` was missing when concatenating directory and filename

Fix

• If `-out` is an absolute path (starts with `/`), use it directly
• For relative paths, add path separator between directory and filename when
  needed

Test Plan

• Build passes
• All 22 existing tests pass
• Added new test cases in x509-ca-test.sh:
  • Absolute `-out` path overrides `new_certs_dir`
  • Relative `-out` path appends to `new_certs_dir` with separator"