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Proton Diffusion Barriers in Iron Sulfide Minerals

Computational study of proton transport through iron sulfide minerals relevant to prebiotic chemistry and protocell membrane design.

Status: Early stage — computational scripts and preliminary results.

What's here

  • neb/ — CI-NEB barrier calculations (MACE-MP-0) for pentlandite, mackinawite, pyrite
  • md/ — Molecular dynamics validation (300K)
  • energy_balance/ — Electrochemical energy balance for pH-gradient driven systems

Preliminary results

Mineral Mechanism E_a (eV) Notes
Pentlandite (2×2×2) Vacancy hop 1.43 Excellent proton barrier
Mackinawite (intra-layer) Grotthuss 0.44 Fast in-plane conductor
Mackinawite (inter-layer) Inter-layer 4.19 Complete blockage
Pyrite (2×2×2) Vacancy hop 0.79 Moderate barrier

Methods

NEB calculations use MACE-MP-0 machine learning interatomic potential with ASE. See individual scripts for parameters.

Requirements

pip install -r requirements.txt

License

Code: MIT. Data: CC-BY-4.0.

AI Collaboration Disclosure

This research was conducted through human–AI collaboration using Claude (Anthropic). Claude Code assisted with script development, literature analysis, and data interpretation. All computational results were independently verified. See exopoiesis.space for project details.

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