I think that the reason is that the plug-in does not correspond to the manual and is absent in the plug-in repository.
Setup
CSS Preprocessor: PostCSS http://codepen.io/ilyar/pen/dvJVaa
Actual result
http://codepen.io/ilyar/pen/dvJVaa.css
@use pobem;
:block(block)
{
color: #0f0;
}
// 'pobem' is not a valid postcss plugin.
Expected Result
rebem/css#5