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As started in another thread, the expmv() function can also be written in the Al-Mohy's algorithm (A. H. Al-Mohy and N. J. Higham. Computing the action of the matrix exponential, with an application to exponential integrators. MIMS EPrint 2010.30, The University of Manchester, 2010; SIAM J. Sci. Comput.), beyond the Krylov, Chebyshev and other usual methods. The MATLAB implementation of the Al-Mohy algorithm (with intensive for-loops) and a C rewritten can be found here and here. It would be good to compare those different methods in Julia and provide parametric interface to competitive algorithms. See also the roadmap of IterativeSolvers.jl.
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